If you want to move your offline files folder in Windows 7, you first have to disable offline files in Windows 7. Disabling offline files is actually pretty easy, the difficult part is moving the offline files folder (tutorial will follow).
How to disable offline files
1. Step Open your Sync Center (Start/All Programs/Accessories/Sync Center):
2. Step Click on “Manage offile files”:
3. Step Click on “Disable Offline Files”:
4. Step Reboot and offline files will be disabled.
Windows 7 Offline Files Location
If you want to know the location of the offline files in Windows 7, read this short tutorial: